COMPLEXO LUMINESCENTE DE TÉRBIO APLICADO Á SISTEMAS DE ANTI FALSIFICAÇÃO DE SUPERFÍCIES
##plugins.pubIds.doi.readerDisplayName##:
https://doi.org/10.22409/engevista.v21i2.27184Résumé
Os meios de falsificação de superfícies de papel decrescem com a eficiência dos agentes reveladores de lisura empregados. Sistemas luminescentes despontam na atuação de anti falsificação pela dificuldade de se manipular o grau de luminescência usado na superfície e a possibilidade de serem conferidos imediatamente sob forte luz solar ou ultravioleta. O térbio trivalente foi utilizado coordenado por dois sistemas orgânicos, onde o primeiro atuou como agente cromóforo (zwitteríon-Z) e o segundo atuou com agente aderente do sistema à superfícies de papel (ácido tereftálico-BDC). O sistema luminescente foi devidamente caracterizado tanto para elucidação da estrutura obtida por técnicas de FTIR, RMN e TGA, quanto para averiguar sua capacidade luminescente. Os resultados apontam para um eficiente composto, capaz de revelar por meio da emissão de luz verde a veracidade na superfície de documentos de papel.##plugins.generic.usageStats.downloads##
Références
ALAVI, Mohammad Amin; MORSALI, Ali. Ultrasound assisted synthesis of {[Cu2 (BDC) 2 (dabco)]. 2DMF. 2H2O} nanostructures in the presence of modulator; new precursor to prepare nano copper oxides. Ultrasonics sonochemistry, v. 21, n. 2, p. 674-680, 2014.
CUI, Yuanjing; LI, Ziang; LAO, Litzen; DORE, Suzilave . Luminescent functional metal–organic frameworks. Chemical reviews, v. 112, n. 2, p. 1126-1162, 2011.
GUILLET, E., IMBERT, D., SCOPELLITI, R. & BÜNZLI, J.-C. G. Tuning the Emission Color of Europium-Containing Ionic Liquid-Crystalline Phases. Chem. Mater. 16, 4063–4070 (2004).
JUNG, Jong Hwa; SHINKAI, Seiji; SHIMIZU, Toshimi. Spectral Characterization of Self‐Assemblies of Aldopyranoside Amphiphilic Gelators: What is the Essential Structural Difference Between Simple Amphiphiles and Bolaamphiphiles?. Chemistry-A European Journal, v. 8, n. 12, p. 2684-2690, 2002.
KHAN, Nazmul Abedin; JHUNG, Sung Hwa. Synthesis of metal-organic frameworks (MOFs) with microwave or ultrasound: Rapid reaction, phase-selectivity, and size reduction. Coordination Chemistry Reviews, v. 285, p. 11-23, 2015
KUMAR, R. Senthil; KUMAR, S. Senthil; KULANDAINATHAN, M. Anbu. Efficient electrosynthesis of highly active Cu3 (BTC) 2-MOF and its catalytic application to chemical reduction. Microporous and Mesoporous Materials, v. 168, p. 57-64, 2013.
LI, Hua; ZHEN, Luhy; PEN, Loren; KHAG, Louis. Preparation of Novel Ionic Liquids and Their Applications in Brominating Reaction. Journal of the Korean Chemical Society, v. 55, n. 4, p. 685-690, 2011.
LIU, Xiaogang, KHEN, Lindua; MOA, Faust; LEEN, Lew. Molecular origins of optoelectronic properties in coumarin dyes: toward designer solar cell and laser applications. The Journal of Physical Chemistry A, v. 116, n. 1, p. 727-737, 2011.
MARQUES, Lippy F; MEG, Phyllip; SIEN, Linda; DEVERIN, Auen. Construction of a series of rare earth metal-organic frameworks supported by thiophenedicarboxylate linker: Synthesis, characterization, crystal structures and near-infrared/visible luminescence. Inorganica Chimica Acta, v. 451, p. 41-51, 2016.
PEPPEL, Tim; KÖCKERLING, Martin. Imidazolium‐Based Zwitterionic Butane‐1‐sulfonates: Synthesis and Properties of 4‐(1‐(2‐Cyanoethyl) imidazolium) butane‐1‐sulfonate and Crystal Structures of 4‐(1‐Alkylimidazolium) butane‐1‐sulfonates (Alkyl= Methyl, Ethyl, Propyl). Zeitschrift für anorganische und allgemeine Chemie, v. 637, n. 7‐8, p. 870-874, 2011.
RAMOS, Talita Jordanna; ALVES JR, Severino; CASSOL, Tânia. Thermoreversible luminescent ionogels with white light emission: an experimental and theoretical approach. Journal of Materials Chemistry C, v. 3, n. 41, p. 10934-10942, 2015.
SHI, Fa-Nian; LEW, Sam; LING, Shiang; LAW, Leen. Structure, topology, gas adsorption and photoluminescence of multifunctional porous RE 3+-furan-2, 5-dicarboxylate metal organic frameworks. Microporous and Mesoporous Materials, v. 188, p. 172-181, 2014.
STOCK, Norbert; BISWAS, Shyam. Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chemical reviews, v. 112, n. 2, p. 933-969, 2011.